导师信息#北京理工大学化学与化工学院研究生院导师介绍#杜大明

北京理工大学化学与化工学院研究生院导师杜大明介绍如下：

教师姓名：杜大明
出生年月：1967年11月
政治面貌：中共党员
所在学科：应用化学
职称：教授，博士生导师
联系电话：010-68914985/68918716
邮箱：dudm@bit.edu.cn
通讯地址：北京市海淀区中关村南大街5号
邮编：100081

教育经历

1992年9月—1995年6月 ，南开大学有机化学专业
，获得理学博士学位 。
1989年9月—1992年7月，南开大学有机化学专业 ，获得理学硕士学位
。
1985年9月—1992年7月
，郑州大学化学专业，获得理学学士学位。

工作经历

2008年9月—目前 ，北京理工大学化工与环境学院
1999年4月—2008年8月，北京大学化学与分子工程学院
1995年7月—1999年3月
，山东大学化学学院
（其间：香港中文大学和香港科技大学）

研究领域

不对称催化合成；有机合成新方法和绿色化学合成；药物及中间体合成

获奖情况

1.教育部新世纪优秀人才支持计划获得者
2.ThiemeJournalAward2009
3.Tetrahedron:AsymmetryMostCitedPaper2004-2007Award
4.第八届北京青年优秀科技论文评选二等奖

社会兼职

教学工作

2015年教学工作
1.本科生《化学制药工艺学》，32学时；
2.本科生《学科进展报告》 ，2学时；
3.硕士研究生《高等有机化学》
，54学时
2014年教学工作
1.本科生《化学制药工艺学》，32学时；
2.本科生《学科进展报告A》 ，2学时；
3.硕士研究生《高等有机化学》
，54学时

论文与著作

1.JiahuanPeng,Bo-LiangZhao,Da-MingDu*.Acombinationofmetaland
organocatalysis:Highlydiastereo-andenantioselectiveconstructionoffluorinated
2-aminocyclopenta[b]pyranderivatives[J].AdvancedSynthesis&Catalysis,2015,
357(16-17),3639-3647.
2.Jun-HuaLi,Da-MingDu*.Phosphine-catalyzedcascadereactionofunsaturated
pyrazoloneswithalkynederivatives:Efficientsynthesisofpyrano[2,3-c]pyrazoles
andspiro-cyclopentanone-pyrazolones[J].AdvancedSynthesis&Catalysis,2015,
DOI:10.1002/adsc.201500675.
3.Jun-HuaLi,Ting-FanFeng,Da-MingDu*.Constructionof
spirocyclopropane-linkedheterocyclescontainingbothpyrazolonesandoxindoles
throughMichael/alkylationcascadereaction[J].TheJournalofOrganicChemistry,
2015,80(22),11369-11377..
4.Bo-LiangZhao,YeLin,Hao-HaoYan,andDa-MingDu*.Squaramide-catalyzed
asymmetriccascadeaza-Michael/Michaeladditionreactionforsynthesisofchiral
trisubstitutedpyrrolidines[J].Organic&BiomolecularChemistry,2015,13(46),
11351-11361.
5.Bo-LiangZhao,Da-MingDu*.Chiralsquaramide-catalyzedMichael/alkylation
cascadereactionfortheasymmetricsynthesisofnitro-spirocyclopropanes[J].
EuropeanJournalofOrganicChemistry,2015,(24),5350-5359.
6.Bo-LiangZhao,Da-MingDu*.Organocatalyticenantioselectivecascade
aza-Michael/Michaeladditionsequenceforasymmetricsynthesisofchiral
spiro[pyrrolidin-3,3'-oxindole]s[J].AsianJournalofOrganicChemistry,2015,4(10),
1120-1126.3
7.Bo-LiangZhao,Da-MingDu*.Chiral-squaramide-catalyzedsulfa-Michael/aldol
cascadereactionsforasymmetricsynthesisofspirothiochromanones[J].Asian
JournalofOrganicChemistry,2015,4(8),778-787.
8.Jun-HuaLi,Da-MingDu*,EnantioselectivecascadedoubleMichaeladditionof
3-nitro-2H-chromenesandacyclicenones:Efficientsynthesisoffunctionalized
tricyclicchromanderivatives[J].Organic&BiomolecularChemistry,2015,13(37),
9600-9609.
9.Jun-HuaLi,Da-MingDu*.Enantioselectivesynthesisofchiralheterocycles
containingbothchromanandpyrazolonederivativescatalysedbyachiral
squaramide[J].Organic&BiomolecularChemistry,2015,13(20),5636-5645.
10.Jun-HuaLi,Da-MingDu*.Enantioselectivesynthesisofbiologicallyactive
dihydropyrano-[2,3-c]pyrazolescatalysedbyachiralsquaramide[J].Chinese
JournalofChemistry,2015,33(4),418–424.
11.Jun-HuaLi,Da-MingDu*.Organocatalyzedenantioselectivecascade
aza-Michael/Michaeladditionfortheconstructionofhighlyfunctionalized
spiropyrazolonetetrahydroquinolines[J].Chemistry-AnAsianJournal,2014,9(11),
3278–3286.
12.YuGao,Da-MingDu*.AsymmetricMichaeladdition/intramolecularcyclization
catalyzedbybifunctionaltertiaryamine-squaramides:constructionofchiral
2-amino-4H-chromene-3-carbonitrilederivatives[J].Chemistry-AnAsianJournal,
2014,9(10),2970–2974.
13.Bo-LiangZhao,LeiLiu,Da-MingDu*.Chiralsquaramide-catalyzed
sulfa-Michael/aldolcascadefortheasymmetricsynthesisofspirocyclic
tetrahydrothiophenechromanonederivatives[J].EuropeanJournalofOrganic
Chemistry,2014,(35),7850–7858.
14.Hai-XiaoHe,Da-MingDu*.OrganocatalyticenantioselectiveStreckerreactionof
iminescontainingathiazolemoietybyusingacinchona-basedsquaramide
catalyst[J].EuropeanJournalofOrganicChemistry,2014,(28),6190–6199.
15.Bo-LiangZhao,Da-MingDu*.Chiralsquaramide-catalysedone-pot
enantioselectivesulfa-Michaeladdition/thioesterificationofthiols
with,-unsaturatedN-acylatedsuccinimides[J].Organic&BiomolecularChemistry,
2014,12(10),1585–1594.
16.Bo-LliangZhao,Da-MingDu*.Catalyticasymmetricconjugateadditionof
various-mercaptoketonesto,-unsaturatedN-acylatedoxazolidin-2-oneswith
bifunctionalorganocatalyst[J].RSCAdvances,2014,4(52),27346–27353.
17.Jun-HuaLi,Da-MingDu*.Enantioselectivesynthesisofpyrazolonederivatives
catalysedbyachiralsquaramidecatalyst[J].RSCAdvances,2014,4(28),14538–
14545.
18.JiahuanPeng,Da-MingDu*.Efficientenantioselectivefluorinationof-keto
esters/amidescatalysedbydiphenylamine-linkedbis(thiazoline)-Cu(OTf)2
complexes[J].RSCAdvances,2014,4(4),2061–2067.
19.Ying-HeLi,Bo-LiangZhao,YuGao,Da-MingDu*.Asymmetricsynthesisof
3-substitutedindolederivativescontainingtetrahydrothiopheneviacascade
Michael/Michaeladditionscatalyzedbyachiralsquaramidecatalyst[J].
Tetrahedron:Asymmetry,2014,25(23),1513–1519.
20.Sheng-JianJia,Da-MingDu*.EnantioselectiveFriedel-Craftsalkylationof
indoleswithβ,γ-unsaturatedα-ketoesterscatalyzedbynewsquaramide-linked
bisoxazoline-Zn(OTf)2complexes[J].Tetrahedron:Asymmetry,2014,25(13-14),980
–988.
21.Hai-XiaoHe,Da-MingDu*.HighlyenantionselectiveMannichreactionofimines
withtert-butylacetoacetatecatalysedbysquaramide[J].Tetrahedron:Asymmetry
2014,25(8),637–643.
22.Bo-LiangZhao,Da-MingDu*.Enantioselectivesynthesisofenollactonesfrom
tandemMichaeladdition/lactonizationcatalyzedbychiralsquaramidecatalyst[J].
Tetrahedron:Asymmetry,2014,25(4),310–317.
23.YiYang,DamingDu*.Enantioselectiveconstructionoffunctionalized
thiochromansviasquaramide-catalyzedasymmetriccascade
sulfa-Michael/Michaeladdition[J].ChineseJournalofChemistry2014,32(9),853–
858.
24.Sheng-JianJia,Da-MingDu*.Enantioselectivechlorinationof-ketoestersand
amidescatalyzedbychiralcopper(II)complexesofsquaramide-linkedbisoxazoline
ligand[J].ChineseChemicalLetters,2014,25(11),1479–1484.
25.WenYang,Da-MingDu*.Cinchona-basedsquaramide-catalysedcascade
aza-Michael-Michaeladdition:enantioselectiveconstructionoffunctionalized
spirooxindoletetrahydroquinolines[J].ChemicalCommunications,2013,49(78),
8842–8844.
26.WenYang,YiYang,Da-MingDu*.Squaramide-tertiaryaminecatalyzed
asymmetriccascadesulfa-Michael/Michaeladditionviadynamickineticresolution:
accesstohighlyfunctionalizedchromanswiththreecontiguousstereocenters[J].
OrganicLetters,2013,15(6),1190–1193.
27.WenYang,Hai-XiaoHe,YuGao,Da-MingDu*.Organocatalyticenantioselective
cascadeaza-Michael/Michaeladditionforthesynthesisofhighlyfunctionalized
tetrahydroquinolinesandtetrahydrochromanoquinolines[J].AdvancedSynthesis&
Catalysis,2013,355(18),3670–3678.
28.Hai-XiaoHe,WenYang,Da-MingDu*.Enantioselectiveaza-Henryreactionof
iminesbearingabenzothiazolemoietycatalyzedbyacinchona-based
squaramide[J].AdvancedSynthesis&Catalysis,2013,355(6),1137–1148.
29.Jun-HuaLi,Da-MingDu*.Squaramide-catalysedenantioselectiveMichael
additionofpyrazolin-5-onestonitroalkenes[J].Organic&BiomolecularChemistry,
2013,11(36),6215–6223.
30.JianhuanPeng,Da-MingDu*.CatalyticasymmetrictandemFriedel-Crafts
alkylation/Michaeladditionreactionforthesynthesisofhighlyfunctionalized
chromans[J].BeilsteinJournalofOrganicChemistry,2013,9,1210–1216.
31.Hai-XiaoHe,Da-MingDu*.Squaramide-catalysedenantionselectiveMannich
reactionofiminesbearingaheterocyclewithmalonates[J].RSCAdvances,2013,
3(37),16349–16358.
32.YangJia,Da-MingDu*.Catalyst-free,one-potthree-component1,3-dipolar
cycloadditionofdiethyl2-aminomalonate,benzaldehydesand
3-nitro-2H-chromenes[J].RSCAdvances,2013,3(6),1970–1975.
33.YuGao,Da-MingDu*.Facilesynthesisofchiral
2-amino-4-(indol-3-yl)-4H-chromenederivativesusingthioureaasthecatalyst[J].
Tetrahedron:Asymmetry,2013,24(20),1312–1317.
34.JuanDong,Da-MingDu*.HighlyenantioselectivesynthesisofWarfarinandits
analogscatalysedbyprimaryamine-phosphinamidebifuncitonalcatalysts[J].
Organic&BiomolecularChemistry,2012,10(40),8125–8131.
35.WenYang,Da-MingDu*.Squaramide-catalysedenantio-anddiastereoselective
sulfa-Michaeladditionofthioaceticacidtoα,β-disubstitutednitroalkenes[J].
Organic&BiomolecularChemistry,2012,10(34),6876–6884.
36.YangJia,WenYang,Da-MingDu*.AsymmetricFriedel-Craftsalkylationof
indoleswith3-nitro-2H-chromenescatalyzedbydiphenylamine-linked
bis(oxazoline)andbis(thiazoline)Zn(II)complexes[J].Organic&Biomolecular
Chemistry,2012,10(24),4739–4746.
37.ChunhuaLuo,YuJin,Da-MingDu*.Simplechiralsulfonamideprimaryamine
catalysedhighlyenantioselectiveMichaeladditionofmalonatestoenones[J].
Organic&BiomolecularChemistry,2012,10(20),4116–4123.
38.WenYang,YangJia,Da-MingDu*.Chiralsquaramide-catalyzedenantioselective
Michaeladditionofmalonitriletochacones[J].Organic&BiomolecularChemistry,
2012,10(2),332–338.
39.JiahuanPeng,Da-MingDu*.AsymmetricFriedel-Craftsalkylationofindoleswith
nitrodienesand2-propargyloxy-β-nitrostyrenescatalyzedby
diphenylamine-linkedbis(oxazoline)-Zn(OTf)2complexes[J].EuropeanJournalof
OrganicChemistry,2012,(21),4042–4051.
40.YuJin,Da-MingDu*.Thesynthesisofphosphineoxide-linkedbis(oxazoline)
ligandsandtheirapplicationinasymmetricallylicalkylation[J].Tetrahedron,2012,
68(18),3633–3640.
41.WenYang,JingsiWang,Da-MingDu*.Chiralsquaramide-catalyzedenantio-
anddiastereoselectiveMichaeladditionof3-substitutedoxindolesto
nitroalkenes[J].Tetrahedron:Asymmetry,2012,23(13),972–980.
42.YuGao,Da-MingDu*.Enantioselectivesynthesisof
2-amino-5,6,7,8-tetrahydro-5-oxo-4H-chromene-3-carbonitrilesusingsquaramide
asthecatalyst[J].Tetrahedron:Asymmetry,2012,23(18-19),1343–1349.
43.YuGao,WenYang,Da-MingDu*.Efficientorganocatalyticasymmetricsynthesis
of2-amino-4H-chromene-3-carbonitrilederivatives[J].Tetrahedron:Asymmetry,
2012,23(5),339–344.
44.ShengjianJia,ChunhuaLuo,DamingDu*.HighlyenantioselectiveMichael
additionofketonetoalkylidenemalonatescatalyzedbybinaphthylsulfonimidesin
water[J].ChineseJournalofChemistry,2012,30(11),2676–2680.
45.WenYang,Da-MingDu*.Chiralsquaramide-catalyzedhighlydiastereo-and
enantioselectivedirectMichaeladditionofnitroalkanestonitroalkenes[J].Chemical
Communications,2011,47(47),12706–12708.
46.WenYang,Da-MingDu*.Chiralsquaramide-catalyzedhighlyenantioselective
Michaeladditionof2-hydroxy-1,4-naphthoquinonestonitroalkenes[J].Advanced
Synthesis&Catalysis,2011,353(8),1241–1246.
47.WenYang,Da-MingDu*.HighlyenantioselectiveHenryreactioncatalyzedby
C2-symmetricmodularBINOL-oxazolineSchiffbasecopper(II)complexgenerated
insitu[J].EuropeanJournalofOrganicChemistry,2011,(8),1552–1556.
48.XianDu,HanLiu,Da-MingDu*.Synthesisandapplicationofdiphenylsulfide
linkedbis(imidazoline)ligands:Dramaticelectroniceffectofligandsoncatalytic
behavior[J].EuropeanJournalofOrganicChemistry,2011,(4),786–793.
49.ChunhuaLuo,Da-MingDu*.HighlyenantioselectiveMichaeladditionof
ketonesandanaldehydetonitroalkenescatalyzedbyabinaphthylsulfonimidein
water[J].Synthesis,2011,(12),1968–1973.
50.WenYang,Da-MingDu*.HighlyenantioselectiveMichaeladditionof
nitroalkanestochalconesusingchiralsquaramidesashydrogenbonding
organocatalysts[J].OrganicLetters,2010,12(23),5450–5453.
51.HanLiu,Da-MingDu*.Developmentofdiphenylamine-linkedbis(imidazoline)
ligandsandtheirapplicationinasymmetricFriedel-Craftsalkylationofindole
derivativeswithnitroalkenes[J].AdvancedSynthesis&Catalysis,2010,352(7),1113
–1118.
52.WenYang,HanLiu,Da-MingDu*.Efficientinsituthree-componentformationof
chiraloxazoline-Schiffbasecopper(II)complexes:towardscombinatoriallibraryof
chiralcatalystsforasymmetricHenryreaction[J].Organic&BiomolecularChemistry,
2010,8(13),2956–2960.
53.ShurongBan,Da-MingDu*,HanLiu,WenYang.Synthesisofnovelbinaphthyl
sulfonimidesandtheirapplicationintheenantioselectiveMichaeladditionof
ketonestonitroalkenes[J].EuropeanJournalofOrganicChemistry,2010,(27),5160
–5164.
54.HanLiu,Da-MingDu*.Immobilizationofdiphenylamine-linkedbis(oxazoline)
ligandsandtheirapplicationinasymmetricFriedel-Craftsalkylationofindole
derivativeswithnitroalkenes[J].EuropeanJournalofOrganicChemistry,2010,(11),
2121–2131.
55.XianDu,HanLiu,Da-MingDu*.Rationaltuningtherigidityofaligandscaffold:
synthesisofdiphenylsulfide-linkedbis(oxazoline)ligandsandtheirapplicationin
asymmetricallylicalkylation[J].Tetrahedron:Asymmetry,2010,21(2),241–246.
56.HanLiu,Neng-DongWng,Da-MingDu*.Directexperimentalevidenceforthe
priorityofflexibleligandskeletoninasymmetricFriedel-Craftsalkylationofindole
withnitroalkenes[J].LettersinOrganicChemistry,2010,7(2),114–120.
57.HanLiu,Da-MingDu*.Recentadvancesinthesynthesisof2-imidazolinesand
theirapplicationsinhomogeneouscatalysis[J].AdvancedSynthesis&Catalysis,
2009,351(4),489–519.
58.WeiLi,HanLiu,Da-MingDu*.Mildmichaeladditionofglycineiminesto
aromaticnitroalkenescatalyzedbyDBUwithLiOTfasanadditive[J].Synlett,2009,
(6),925–928.
59.JinWang,HanLiu,Da-MingDu*.Diphenylamine-derivedbis-hydroxyamide
catalyzedasymmetricboranereductionofprochiralketones[J].Tetrahedron:
Asymmetry,2009,20(5),605–609.
60.Qun-ShengGuo,Da-MingDu*.Thepracticalsynthesisofdoubleaxialchiral
guanidines[J].LettersinOrganicChemistry,2009,6(3),197–202.
61.HanLiu,WeiLi,DaMingDu*.Modificationofdiphenylamine-linked
bis(oxazoline)ligands:tuningofelectroniceffectandrigidityofligandskeleton[J].
ScienceinChinaSeriesB:Chemistry,2009,52(9),1321–1330.
62.NingChen,MinZhu,WeiZhang,Da-MingDu,JiaxiXu*.Synthesisof
gem-disubstitutedtaurinesbytheregioselectivering-openingof2,2-disubstituted
aziridineswithsodiumbisulfiteandsulfite[J].Aminoacids,2009,37(2),309-313.
63.Qun-ShengGuo,Da-MingDu*,JiaxiXu.Thedevelopmentofnewdoubleaxially
chiralphosphoricacidsandtheircatalyticasymmetrictransferhydrogenationof
quinolines[J].AngewandteChemie,InternationalEdition,2008,47(4),759–762.
64.Wen-MingZhou,HanLiu,Da-MingDu*.Organocatalytichighlyenantioselective
Michaeladditionof2-hydroxy-1,4-naphthoquinonestonitroalkenes[J].Organic
Letters,2008,10(13),2817–2820.
65.HanLiu,Shao-FengLu,JiaxiXu,Da-MingDu*.AsymmetricFriedel-Crafts
alkylationofelectron-richN-heterocycleswithnitroalkenescatalyzedby
diphenylamine-tetheredbis(oxazoline)andbis(thiazoline)-Zn(II)complexes[J].
Chemistry-AnAsianJournal,2008,3(7),1111–1121.
66.Huihui?Li,GuYuan,*DamingDu.Investigationofformation,recognition,
stabilization,andconversionofdimericG-quadruplexesofHIV-1integrase
inhibitorsbyelectrosprayionizationmassspectrometry[J].JournaloftheAmerican
SocietyofMassSpectrometry,2008,19(4),550–559.
67.BoyuanWang,WeiZhang,LeileiZhang,Da-MingDu,GangLiu,JiaxiXu*.
VersatilesynthesisoffreeandN-benzyloxycarbonylprotected2,2-disubstituted
taurines[J].EuropeanJournalofOrganicChemistry,2008,(2),350–355.
68.JuanjuanDu,ZhiyiLi,Da-MingDu,JiaxiXu*.Unexpectedinfluenceanditsorigin
inrationallytuningtheelectroniceffectofcatalystsintheasymmetricborane
reductionofketones[J].JournalofMolecularCatalysisA:Chemistry,2008,284(1),
40–45.
69.WeiZhang,BoyuanWang,NingChen,Da-MingDu,JiaxiXu*.Expeditiousand
practicalsynthesisofvarioussubstitutedtaurinesfromaminoalcohols[J].Synthesis,
2008,(2),197–200.
70.MinZhu,LiboHu,NingChen,Da-MingDu,andJiaxiXu*.Synthesisof
NH-aziridinesfromvicinalaminoalcoholsviatheWenkerreaction:scopeand
limitation[J].LettersinOrganicChemistry,2008,5(3),212–217.
71.JuanjuanDu,ZhiyiLi,Da-MingDu,JiaxiXu*.Improvingenantioselectivityvia
rationallytuningelectroniceffectsofcatalystsintheorganocatalyticasymmetric
aldolreaction[J].Arkivoc,2008,Part(xvii),145–156.
72.HanLiu,JiaxiXu,Da-MingDu*.AsymmetricFriedel-Craftsalkylationof
methoxyfuranwithnitroalkenescatalyzedbydiphenylamine-tethered
bis(oxazoline)-Zn(II)complexes[J].OrganicLetters,2007,9(23),4725–4728.
73.LiboHu,HuiZhu,Da-MingDu,JiaxiXu*.Efficientsynthesisoftaurineand
structurallydiversesubstitutedtaurinesfromaziridines[J].TheJournalofOrganic
Chemistry,2007,72(12),4543–4546.
74.BonanLi,ShuzongCai,Da-MingDu,JiaxiXu*.Synthesisofphosphinopeptides
viatheMannichligation[J].OrganicLetters,2007,9(12),2257–2260.
75.BonanLi,YikaiWang,Da-MingDu,JiaxiXu*.Notableandobviousketene
substituent-dependenteffectoftemperatureonthestereoselectivityinthe
Staudingerreaction[J].TheJournalofOrganicChemistry,2007,72(3),990–997.
76.LiboHu,YikaiWang,BonanLi,Da-MingDu,JiaxiXu*.Diastereoselectivityinthe
Staudingerreaction:ausefulprobeforinvestigationofnonthermalmicrowave
effects[J].Tetrahedron,2007,63(38),9387–9392.
77.LingeMa,PengJiao,QihanZhang,Da-MingDu,JiaxiXu*.Ligandandsubstrate
pi-stackinginteractioncontrolledenantioselectivityinthecatalyticasymmetric
aziridination[J].Tetrahedron:Asymmetry,2007,18(7),878–884.
78.XiaoWang,HanLiu,Da-MingDu,JiaxiXu*.Effectoftheboranesourceonthe
enantioselectivityinthechiraloxazaborolidine-catalyzedasymmetricborane
reductionofketones[J].HeteroatomChemistry,2007,18(7),740–746.
79.李伯男，梁勇 ，焦雷
，胡立博，杜大明 ，许家喜*.3-(噻吩-2-基)-β-内酰胺的合成及其立
体化学[J].化学学报,2007,65(16),1643–1648.
80.Shao-FengLu,Da-MingDu*,JiaxiXu,Shi-WeiZhang.Asymmetricconjugate
additionofnitroalkanestonitroalkenescatalyzedbyC2-symmetrictridentate
bis(oxazoline)andbis(thiazoline)zinccomplexes[J].JournaloftheAmerican
ChemicalSociety,2006,128(23),7418–7419.
81.Shao-FengLu,Da-MingDu*,JiaxiXu.EnantioselectiveFriedel-Craftsalkylation
ofindoleswithnitroalkenescatalyzedbybifunctionaltridentatebis(oxazoline)-Zn(II)
complex[J].OrganicLetters,2006,8(10),2115–2118.
82.Da-MingDu*,TaoFang,JiaxiXu,Shi-WeiZhang.Structurallywell-defined,
recoverableC3-symmetrictris(-hydroxyphosphoramide)-catalyzed
enantioselectiveboranereductionofketones[J].OrganicLetters,2006,8(7),1327–
1330.
83.TaoFang,JiaxiXu,Da-MingDu*.Highlyenantioselectiveboranereductionof
prochiralketonescatalyzedbyC3-symmetrictripodal-hydroxyamides[J].Synlett,
2006,(10),15591563.
84.TaoFang,JiaxiXu,Da-MingDu*.FacilesynthesisofC3-symmetrictripodal
-hydroxyamideligandsandtheirTi(IV)complex-catalyzedasymmetricadditionof
diethylzinctoaldehydes[J].LettersinOrganicChemistry,2006,3(10),780–786.
85.YikaiWang,YongLiang,LeiJiao,Da-MingDu,JiaxiXu*.Doreactionconditions
affectthestereoselectivityintheStaudingerreaction?[J].TheJournalofOrganic
Chemistry,2006,71(18),69836990.
86.LingeMa,Da-MingDu,JiaxiXu.Asymmetricaziridinationof1,3-dienes
catalyzedbybisoxazoline-coppercomplexes[J].Chirality,2006,18(8),575–580.
87.XiaoWang,YikaiWang,Da-MingDu,JiaxiXu*.Solvent-free,AlCl3-promoted
tandemFriedel-Craftsreactionofarenesandaldehydes[J].JournalofMolecular
CatalysisA:Chemistry,2006,255(1-2),31–35.
88.JiaxingHuang,Da-MingDu,JiaxiXu*.Facilesynthesisof1,1-disubstituted
taurines[J].Synthesis,2006,(2),315–319.
89.HanLiu,Da-MingDu,JiaxiXu*.Effectofthesecondaryreductiononthe
enantioselectivityandfunctionofadditivesintheoxazaborolidine-catalyzed
asymmetricboranereductionofketones[J].HelveticaChimicaActa,2006,89(5),
1067–1074.
90.马琳鸽,杜大明,许家喜.在不对称氮杂环丙烷化中双噁唑啉配位空间大小对对映选择
性的影响[J].有机化学,2006,26(4),568–572.
91.王一恺,杜大明,许家喜*.微波对烯酮和亚胺形成-内酰胺顺反选择性的影响[J].辽宁石
油化工大学学报,2006,26(4),94–95,99.
92.TaoFang,Da-MingDu,*Shao-FengLu,JiaxiXu*.SynthesisofC3-Symmetric
tris(-hydroxyamide)ligandsandtheirTi(IV)complex-catalyzedenantioselective
alkynylationofaldehydes[J].OrganicLetters,2005,7(11),2081–2084.
93.Da-MingDu,*Shao-FengLu,TaoFang,JiaxiXu*.AsymmetricHenryreaction
catalyzedbyC2-symmetrictridentatebis(oxazoline)andbis(thiazoline)complexes:
metal-controlledreversalofenantioselectivity[J].TheJournalofOrganicChemistry,
2005,70(9),3712–3715.
94.LingeMa,Da-MingDu,JiaxiXu*.Rationaltuningchelatesizeofbis-oxazoline
ligandstoimproveenantioselectivityintheasymmetricaziridinationof
chalcones[J].TheJournalofOrganicChemistry2005,70(24),10155–10158.
95.JiaxingHuang,FeiWang,Da-MingDu,JiaxiXu*.Anexpeditioussynthesisof
1-substitutedandcyclictaurines[J].Synthesis,2005,(13),2122–2128.
96.Zhan-YueWang,Da-MingDu*,Jia-XiXu.Synthesisofnovelchiralsemicrown
ether-likebis(oxazoline)ligandsandapplicationinenantioselective
cyclopropanationofstyrene[J].SyntheticCommunications,2005,35(2),299–313.
97.HuiChen,Da-MingDu,BinFu,MeiyuHe.Investigationonmassspectra
fragmentationmechanismofC2-symmetricchiralbis(oxazolines)and
bis(thiazolines)[J].ChineseJournalofChemistry,2005,23(6),720–724.
98.Da-MingDu,PaulR.Carlier*.Developmentofbivalentacetylcholinesterase
inhibitorsaspotentialtherapeuticdrugsforalzheimer’sdisease[J].Current
PharmaceuticalDesign,2004,10(25),3141–3156.
99.Shao-FengLu,Da-MingDu,*Shi-WeiZhang,JiaxiXu*.Facilesynthesisof
C2-symmetrictridentatebis(thiazoline)andbis(oxazoline)ligandsandtheir
applicationintheenantioselectiveHenryreaction[J].Tetrahedron:Asymmetry,
2004,15(21),3433–3441.
100.BinFu,Da-MingDu*,JianboWang.SynthesisofnovelC2-symmetricchiral
bis(oxazoline)ligandsandtheirapplicationintheenantioselectiveadditionof
diethylzinctoaldehydes[J].Tetrahedron:Asymmetry,2004,15(1),119–126.
101.BinFu,Da-MingDu,*QingXia.C2-symmetricchiralbis(thiazoline)and
bis(oxazoline)ligandsandtheirapplicationinthecatalyticallylicalkylation[J].
Synthesis,2004,(2),221–226.
102.Yong-XinZhang,Da-MingDu,*XiaoChen,Shao-FengLü,Wen-TingHua.
Enantiospecificsynthesisofpyridinylmethylpyrrolidinemethanolsandcatalytic
asymmetricboranereductionofprochiralketones[J].Tetrahedron:Asymmetry,
2004,15(1),177–182.
103.BinFu,DaMingDu,*QingXia.Convenientsynthesisofbis(oxazoline)
dicarboxylatederivatives[J].ChineseChemicalLetters,2004,15(4),383–
385.
104.XiaoChen,YongXinZhang,DaMingDu,WenTingHua*.Newchiralpyridine
prolinolderivativesandpreliminarystudyonasymmetriccatalyticreaction[J].
ChineseChemicalLetters,2004,15(2),167–168.
105.WeifengShi,NanJiang,ShiweiZhang,WeimingWu,DamingDu,JianboWang*.
Unusualreactionofbeta-hydroxyalpha-diazocarbonylcompoundswith
Cl3CCN/NaHandRh(II)-catalyzedreactionofbeta-trichloroacetylamino
alpha-diazocarbonylcompounds[J].OrganicLetters,2003,5(13),2243–2246.
106.Da-MingDu,*BinFu,Wen-TingHua.Novelchiraldibenzo[a,c]cycloheptadiene
bis(oxazoline)andcatalyticenantioselectivecyclopropanationofstyrene[J].
Tetrahedron,2003,59(11),1933–1938.
107.XiaoChen,Da-MingDu,Wen-TingHua*.Synthesisofnovelchiralpolyamide
macrocyclescontainingpyridylside-armandtheirmolecularrecognition
properties[J].Tetrahedron:Asymmetry,2003,14(8),999–1007.
108.Dong-ChengXu,Da-MingDu,*NanJi,Zhan-YueWang,Wen-TingHua.
SynthesisofnovelchiralC2-symmetricbisoxazolineligandscontaining
2,5-di(m-substituted)phenyl-1,3,4-oxadiazole[J].SyntheticCommunications,2003,
33(14),2563–2574.
109.Zhan-YueWang,Da-MingDu,*DiWu,Wen-TingHua*.Studiesonthe
synthesisofnovelchiralnaphthylenebisoxazolineligands[J].Synthetic
Communications,2003,33(8),1275–1283.
110.HuiChen,Da-MingDu,Wen-TingHua,MeiyuHe,*BinXin.Studyofthe
fragmentationmechanismofnovelfunctionalizedmacrocyclesbyFourier
transformioncyclotronresonancemassspectrometry[J].JournalofMass
Spectrometry,2003,38(8),839–844.
111.BinFu,Da-MingDu*.AsymmetricDiels-Alderreactioncatalyzedbynovelchiral
dibenzo[a,c]cycloheptadienebis(oxazoline)metalcomplexes[J].ChineseJournalof
Chemistry,2003,21(6),597–599.
112.杜大明,*陈晓,花文廷.离子液体介质中有机合成及催化不对称反应研究新进展[J].有
机化学,2003,23(4),331–343.
113.杜大明,*花文廷.大环手性磷酰胺对氨基酸衍生物的分子识别研究[J].高等学校化学
学报,2003,24(3),442–448.
114.Zhan-YueWang,Da-MingDu,*DiWu,Wen-TingHua,Xiang-LinJin.Synthesis
andCrystalStructureofN-(1’-Phenyl-2’
-hydroxyethyl)-2,3-naphthylenedicarboximide[J].ChemicalResearchinChinese
Universities,2003,19(2),160–164.
115.Da-MingDu,*XiaoChen,Wen-TingHua,Xiang-LinJin.Reinvestigationthe
reactionofsalicyclicchloridewithsalicyclicamideandX-raycrystalstructureofa
newmacrocyclicpolyester[J].ChineseJournalofStructuralChemistry,2003,22(5),
512–516.
116.Hai-ChenWu,Da-MingDu,Wen-TingHua,*Xiang-LinJin.Synthesisandcrystal
structureofnovelchiralo-hydroxyphenyloxazolinemetalcomplexes[J].Chinese
JournalofStructuralChemistry,2003,22(2),155–160.
117.Da-MingDu,*Zhan-YueWang,Dong-ChengXu,Wen-TingHua.Synthesisof
novelchiralbisoxazolineligandscontaining2,5-diaryl-1,3,4-oxadiazoleand
enantioselectivecyclopropanationofstyrene[J].Synthesis,2002,(16),2347–2352.
118.XiaoChen,Da-MingDu,Wen-TingHua*.Aconvenientmethodforsynthesisof
trans-4-cyclohexyl-L-proline[J].Tetrahedron:Asymmetry,2002,13(1),43–46.
119.XiaoChen,DaMingDu,WenTingHua*.SynthesisofnovelC2-symmetricchiral
polyamidemacrocyclescontainingpyridylside-arm[J].ChineseChemicalLetters,
2002,13(11),1037–1038.
120.杜大明,*花文廷.催化不对称Michael加成反应的新进展[J].有机化学,2002,22(3),
164–173.
121.周灵萍,杜大明,李宣文,*王少坤,周爱秋,刘建.NaBr/KZSM-5催化剂在甲苯氧化甲
基化反应中的催化性能[J].北京大学学报(自然科学版),2002,38(2),153–158.
122.Da-MingDu,*Wen-TingHua.One-potsynthesisofmacrocyclicchiral
phosphoramidates[J].SyntheticCommunications,2001,31(20),3197–3203.
123.Da-MingDu,*Wen-TingHua,Xiang-LingJin.Synthesisandcrystalstructureof
twonewmacrocyclicphosphoramidatescontainingglycineethylesterand
2,5-diaryl-1,3,4-oxadiazole[J].JournalofMolecularStructure,2001,561(1-3),145–
152.
124.Da-MingDu,*Wen-TingHua,Zhe-MingWang,Chun-HuaYan.Newchiral
macrocyclicphosphoramidateself-associatedbyanintermolecularN-HO=P
hydrogenbond[J].HeteroatomChemistry,2001,12(6),480–484.
125.Da-MingDu,*Wen-TingHua,Ling-PingZhou,Jian-WuWang,Xiang-LinJin.
Preparationandcrystalstructureofa1:1inclusioncompoundof
1,4,11,14-tetramethoxy-dibenzo[b,n]tetraphenylenewithpyridine[J].Journalof
MolecularStructure,2001,560(1-3),23–28.
126.杜大明,*王永梅,孟继本,周秀中.双核有机金属化合物的光化学反应[J].有机化学,
2001,21(5),350–355.
127.PaulR.Carlier,*Da-MingDu,Yi-FanHan,JingLiu,EmanuelePerola,IanD.
Williams,Yuan-PingPang.DimerizationofaninactivefragmentofHuperzineA
producesadrugwithtwicethepotencyofthenaturalproduct[J].Angewandte
Chemie,InternationalEdition,2000,39(10),1775–1777.
128.Da-MingDu,*Wen-TingHua,Jian-WuWang,Xiang-LinJin.Synthesesand
molecularself-assemblyofchiralphosphoramdates[J].ChineseJournalof
Chemistry,2000,18(5),764–769.
129.Da-MingDu,*Lin-PingZhou,Jian-WuWang,Shao-KunWang.Practical
synthesisofnewfunctionalizedtetraphenylenes[J].ChineseJournalofChemistry,
2000,18(3),441–443.
130.WeiLiu,JianzhuangJiang,*DamingDu,DdennisP.Arnold.Synthesisand
spectroscopicpropertiesofhomolepticbis(octakis(octyloxy)phthalocyaninato)rare
earth(III)sandwichcomplexes[J].AustralianJournalofChemistry,2000,53(2),131–
135.
131.TebelloNyokong,FumioFuruya,NagaoKobayashi,DamingDu,WeiLiu,
JianzhuangJiang*.Comparativespectroscopicandelectrochemicalpropertiesof
bis(octakis-(dodecylthio)naphthalocyaninato)europium(III)and
bis(tetra-tert-butylnaphthalocyaninato)europium(III)complexes[J].Inorganic
Chemistry,2000,39(1),128–135.
132.JianzhuangJiang,*WeiLiu,Ka-WoPoon,DamingDu,DennisP.Arnold,Dennis
K.P.Ng.Synthesis,spectroscopic,andelectrochemicalpropertiesofrareearth
double-deckerswithtetra(tert-butyl)-2,3-naphthalocyaninatoligands[J].European
JournalofInorganicChemistry,2000,(1),205–209.
133.Xiao-PingYang,Da-MingDu,QiLi,ThomasC.W.Mak,HenryN.C.Wong*.
Synthesis,structureandinclusionpropertiesof
1,4,15,18-tetrahedro-1,4,15,18-tetraoxodibenzo-[b,h]tetraphenylene[J].Chemical
Communications,1999,(16),1607–1608.
134.PaulR.Carlier,*Da-MingDu,YifanHan,JingLiu,Yuan-PingPan.Potent,easily
synthesizedHuperzineA-Tacrinehybridacetylcholinesteraseinhibitors[J].
Bioorganic&MedicinalChemistryLetters,1999,9(16),2335–2338.
135.JianzhuangJiang,*DamingDu,M.T.M.Choi,J.L.Xie,DennisK.P.Ng.
SynthesisandspectroscopiccharacterizationofheterolepticEuropium(III)
double-deckerscontaining2,3-naphthalo-cyaninatoandtetra(4-pyridyl)-
porphyrinatoligands[J].ChemicalLetters,1999,(3),261–262.
136.姜建壮,*吴基培,杜大明,孙思修三明治型金属卟啉 、酞菁配合物功能材料[J].大学
化学,1999,14(2),5–8.
137.Da-MingDu,FengXue,HenryN.C.Wong,*ThomsC.W.Mak.Reactionof
2-methylnaphthalenewithhexachlorocyclopentadieneandstructural
characterizationofanewaddition-substitutionproduct[J].JournalofChemical
Crystallography,1998,28(11),787–790.
138.Da-MingDu,*Ling-PingZhou,Yong-MeiWang,Ji-BenMeng.Synthesisand
photoreactionofpolymethylenediaminebis(4-methyl-7-coumarinyl)oxyacetic
amides[J].ChineseJournalofChemistry,1998,16(5),468–472.
139.Yong-MeiWang,ZhongWen,Xiao-MinChen,Da-MingDu,T.Matsuura,Ji-Ben
Meng*.Researchonphotochemicalandthermochemicalreactionsbetweenindole
andquinonesintheabsenceofsolevent[J].J.HeterocyclicChemistry,1998,35(2),
313–316.
140.杜大明*,王永梅,孟继本.微环境对长链香豆素酯光化学和光物理过程的影响[J].高等
学校化学学报,1998,19(10),1611–1613.
141.杜大明,*周灵萍,孟继本,王永梅.微环境条件影响的光化学反应研究进展[J].合成化
学,1998,6(3),265–271.
142.杜大明,王永梅,张慧萍,孟继本,*周秀中.非共轭双发色团体系的光化学I.双香豆
素氧乙酸多次甲基二醇酯的合成及光反应研究[J].化学学报,1997,55(2),189–195.
143.王永梅,杜大明,李晓陆,孟继本,*周秀中.微环境影响下的乙酰基香豆素与吲哚的固
相光反应[J].有机化学,1997,17(5),433–437.
144.Yong-MeiWang,Da-MingDu,Ji-BenMeng,*Xiu-ZhongZhou,LeiWang.
PhotochemistryofnonconjugatedbischromophoricsystemsIII.Synthesisand
photoreactionofpoly(ethyleneglycol)biscoumarinyloxyacetates[J].Chinese
JournalofChemistry,1997,15(2),169–173.
145.Xiao-LiuLi,Da-MingDu,Yong-MeiWang,Ji-BenMeng*.Solidstatereactions
ofnitrogenousheterocycliccompoundsI.Solidstatereactionsof
3-methyl-1-phenyl-5-pyrazolonewithcarbonylcompounds[J].ScienceinChina
(SeriesB),1997,40(2),205–214.
146.Xiao-LiuLi,Yong-MeiWang,Da-MingDu,ZhongWen,Guo-XiangXiong,
Ji-BenMeng*.SolidstatereactionsofnitrogenousheterocycliccompoundsII.Solid
statereactionsofindoleandcarbonylcompounds[J].ScienceinChina(SeriesB),
1997,40(3),270–277.
147.杜大明,王永梅,孟继本,*周秀中,王国昌,梁丽君,高焕.非共轭双发色团体系的光
化学(II)长链双香豆素的光环化反应和荧光光谱研究[J].高等学校化学学报,1996,17(7),
1074–1077.
148.杜大明,王永梅,孟继本*,周秀中,张慧萍.乙酰基香豆素及其衍生物与吲哚的固相光
反应研究[J].高等学校化学学报,1996,17(2),252–254.
149.杜大明,王永梅,孟双明,梁树森,孟继本,*周秀中.1-苯基-3-甲基-5-吡唑啉酮与二
羰基化合物的固相反应研究[J].高等学校化学学报,1996,17(1),81–84.
150.Yong-MeiWang,Da-MingDu,Xiao-MinChen,Ji-BenMeng,*Hui-PingZhang.
Photochemicalandthermalreactionsofquinoneswithp-chlorothiophenolinsolid
stateandinsolution[J].ChemicalResearchinChineseUniversities,1996,12(3),235
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151.HuanGao,Guo-ChangWang,Li-JunLiang,Bin-LinHe,Da-MingDu,
Yong-MeiWang,Ji-BenMeng*.Microenvironmentaleffectontheintramolecular
photochemicalinteractionofbiscoumarinylcompoundscontainingalkylchains[J].
ChineseChemicalLetters,1996,7(8),753–755.
152.Da-MingDu,Yong-MeiWang,Ji-BenMeng,*Shuang-MingMeng,Xiu-Zhong
Zhou,Hong-Gen.Photocycloadditionof(4-methyl-7-coumarinyl)oxyaceticacid
propanedioldiesterandX-raycrystalstructureofproduct[J].ChineseJournalof
StructuralChemistry,1995,14(4),272–276.
153.Da-MingDu,Shuang-MingMeng,Yong-MeiWang,Ji-BenMeng,*Xiu-Zhong
Zhou,YingZhu.Solidstatesynthesisandcrystalstructureof
3-methyl-1-phenyl-4-phenylbenzoyl-methylene-5-pyrazolone[J].ChineseJournal
ofStructuralChemistry,1995,14(4),277–280.
154.Da-MingDu,Shuang-MingMeng,Yong-MeiWang,Ji-BenMeng,*Xiu-Zhong
Zhou.Solidstatereactionofaromaticketoneswithheteroaromatics[J].Chinese
JournalofChemistry,1995,13(6),520–524.
155.Da-MingDu,Yong-MeiWang,Guo-XiangXiong,Wen-GuangWang,Ji-Ben
Meng*.Solidstatephotochemistryofnitrobenzaldehydes[J].ChemicalResearchin
ChineseUniversities1995,11(2),111–116.
156.孟继本,*王文广,杜大明,熊国祥,王永梅.含氮杂环化合物的固相光化学[J].化学学报,1995,53(6),595–602.
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158.Ji-BenMeng;Da-MingDu,Guo-XiangXiong,Wen-GuangWang,Yong-MeiWang,H.Koshima,T.Matsuura*.Adualpathwayinthesolid-statephotoreactionofnitrobenzaldehydeswithIndole[J].JournalofHeterocyclicChemistry,1994,31(1),121–124.
159.Ji-BenMeng,*Da-MingDu,Yong-MeiWang,Hong-GenWang,Ru-JiWang.
ThesynthesisandX-raycrystalstructurestudiesof(di-3-indolyl)methylferrocene[J].
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160.Ji-BenMeng,Wen-GuangWang,Guo-XiangXiong,Yong-MeiWang,De-Chao
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161.Ji-BenMeng,*Da-MingDu,Yong-MeiWang,Hong-GenWang,Ru-JiWang.
Solidstatephotochemicalsynthesisofanovelhostcompoundmethyl
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162.Ji-BenMeng,*Da-MingDu,Guo-XiangXiong,Wen-GuangWang,Yong-Mei
Wang.Thesolidstatecontrolledphotochemicalreactionofnitrobenzaldehydes
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indole[J].ChineseChemicalLetters,1992,3(4),247.

科研项目

1.方酰胺催化不对称加成与串联反应合成杂环化合物研究.(国家自然科学基金面上项目
，项目负责人)
2.模块组装合成多齿手性配体及在不对称催化反应中的应用研究.(国家自然科学基金面上项目，项目负责人)
3.手性方酰胺催化不对称串联反应合成含氮杂环化合物研究.(元素有机化学国家重点实验室基金项目 ，项目负责人)
4.新型手性配体及催化剂设计合成与高效不对称催化研究.?(北京理工大学科技创新计划重大项目培育专项计划,项目负责人)
5.三齿手性配体的合成与不对称催化反应研究.(国家自然科学基金面上项目，项目负责人)
6.新型C3对称性手性配体的合成及其在不对称催化反应中的应用.(国家自然科学基金面上项目
，项目负责人)
7.教育部新世纪优秀人才支持计划.(国家教育部人才项目，项目负责人)
8.有机合成化学与方法学.(国家自然科学基金会创新群体项目 ，项目参加人)
9.新杂环手性配体的合成与不对称催化反应研究.(国家自然科学基金面上项目
，项目负责人)
10.新手性双噁唑啉催化剂的设计合成与不对称催化反应研究.(国家自然科学基金面上项目，项目负责人)
11.手性磷酰胺主体化合物的合成
、分子识别及应用基础研究.(国家自然科学基金面上项目 ，项目负责人)
12.BG-1原料药合成实验工艺的开发研究.(横向项目
，项目共同负责人)
13.新模板剂的合成.(横向项目，项目负责人)
14.新型苯并环辛四烯超分子体系的设计合成和结构鉴定.(留学归国人员启动基金项目 ，项目负责人)
15.手性磷酰胺主体的合成与分子识别.(中国博士后科学基金项目
，项目负责人)

授权专利

1.DimericCompounds(Dimeric5-amino-5,6,7,8-tetrahydroquinolinonesandtheir
pharmaceuticaluse).UnitedKingdomPatentNo:GB2360518A.
2.DimericCompounds(Dimeric5-amino-5,6,7,8-tetrahydroquinolinonesandtheir
pharmaceuticaluse).UnitedStatesPatentNo:US6472408B1.
3.一种简便合成康普立停A-4前药的方法.中国专利号:ZL02120895.6
4.手性二苯并[a,c]环庚二烯双噁唑啉配体化合物及其制备与应用.中国专利号:ZL03101899.8
5.一种有机磷酸催化剂及其制备方法和应用.中国专利号:ZL200710175800.7
6.一种双咪唑啉二苯胺类化合物及其制备方法.中国专利号:ZL200910243257.9.
7.一种噁唑啉西佛碱配体金属络合物催化剂及其应用.中国专利号:ZL201010034468.4
8.一种三苯基氧磷连接双噁唑啉配体化合物及其制备方法.中国专利号:ZL201110255694.X
9.取代牛磺酸衍生物及其制备方法.中国专利号:ZL200510011724.7
10.亚膦酰肽及其制备方法.中国专利号:ZL200710086598.0
11.牛磺酸及其衍生物制备.中国专利号:ZL200710064146.2
12.一种取代牛磺酸的制备方法.中国专利号:ZL200710175915.6
13.光酸聚合物掺杂的螺噁嗪或螺吡喃可逆光致变色薄膜及其制备方法和用途.中国专利号:
ZL200710099452.X